Copper( II ) and Zinc( II ) Complexes Can Fix Atmospheric Carbon Dioxide | Zendy

Kong LingYan | Zendy; Zhang ZhengHua | Zendy; Zhu HuiFang | Zendy; Kawaguchi Hiroyuki | Zendy; Okamura Takaaki | Zendy; Doi Mototsugu | Zendy; Chu Qian | Zendy; Sun WeiYin | Zendy; Ueyama Norikazu | Zendy

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Copper( II ) and Zinc( II ) Complexes Can Fix Atmospheric Carbon Dioxide

Author(s) -

Kong LingYan,

Zhang ZhengHua,

Zhu HuiFang,

Kawaguchi Hiroyuki,

Okamura Takaaki,

Doi Mototsugu,

Chu Qian,

Sun WeiYin,

Ueyama Norikazu

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500587

Subject(s) - carbon dioxide , zinc , chemistry , copper , carbonate , ligand (biochemistry) , imidazole , carbon dioxide in earth's atmosphere , inorganic chemistry , polymer chemistry , stereochemistry , organic chemistry , receptor , biochemistry

Carbonato bridges from atmospheric carbon dioxide : The copper( II ) and zinc( II ) complexes of the novel imidazole‐containing polyamine ligand N 1 ‐(2‐aminoethyl)‐ N 1 ‐(2‐imidazolethyl)ethane‐1,2‐diamine are found to fix carbon dioxide by hydration to μ 3 ‐carbonate ligands. This is revealed by IR and solid‐state 13 C NMR spectroscopic and X‐ray crystallographic studies of the two‐dimensional complexes (see picture).

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