Asymmetric Carboselenenylation Reaction of Alkenes with Aromatic Compounds | Zendy

Okamoto Kazuki | Zendy; Nishibayashi Yoshiaki | Zendy; Uemura Sakae | Zendy; Toshimitsu Akio | Zendy

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Asymmetric Carboselenenylation Reaction of Alkenes with Aromatic Compounds

Author(s) -

Okamoto Kazuki,

Nishibayashi Yoshiaki,

Uemura Sakae,

Toshimitsu Akio

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500573

Subject(s) - stereocenter , chemistry , trifluoromethanesulfonate , moiety , aryl , carbon atom , friedel–crafts reaction , organic chemistry , ring (chemistry) , medicinal chemistry , enantioselective synthesis , catalysis , alkyl

High diastereoselectivity is attained in the carboselenenylation reaction of simple alkenes with aromatic compounds by using a C 2 ‐symmetric areneselenenyl triflate (see scheme). This asymmetric Friedel–Crafts‐type reaction is a convenient procedure for the preparation of chiral hydrocarbons bearing an aryl moiety at the stereogenic carbon atom. Tf=trifluoromethanesulfonyl; M.S.=molecular sieves.

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