A [70]Fullerene Chloride, C 70 Cl 16 , Obtained by the Attempted Bromination of C 70  in TiCl 4 | Zendy

Troyanov Sergey I. | Zendy; Popov Alexey A. | Zendy

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A [70]Fullerene Chloride, C 70 Cl 16 , Obtained by the Attempted Bromination of C 70 in TiCl 4

Author(s) -

Troyanov Sergey I.,

Popov Alexey A.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500476

Subject(s) - fullerene , chlorine , halogenation , chemistry , chloride , molecule , crystallography , chlorine atom , crystal (programming language) , photochemistry , inorganic chemistry , medicinal chemistry , organic chemistry , computer science , programming language

Tales of the unexpected : The [70]fullerene chloride C 70 Cl 16 resulted from the reaction of [70]fullerene with a mixture of Br 2 and TiCl 4 . A single‐crystal X‐ray crystallographic study revealed the presence of two isomers of C 70 Cl 16 , both containing a belt of ten chlorine atoms around the equator and a skew pyramidal cap of six chlorine atoms on the pole of the C 70 Cl 16 molecule (see picture).

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