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Monomeric Thallium( I ) Complexes of Fluorinated Triazapentadienyl Ligands
Author(s) -
Dias H. V. Rasika,
Singh Shreeyukta,
Cundari Thomas R.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200500401
Subject(s) - thallium , monomer , ligand (biochemistry) , aryl , chemistry , atom (system on chip) , stereochemistry , medicinal chemistry , polymer chemistry , combinatorial chemistry , organic chemistry , computer science , biochemistry , operating system , polymer , receptor , alkyl
Rare examples of thallium monocoordination? Polyfluorinated triazapentadienes HN[C(C 3 F 7 )NAr] 2 with bulky aryl substituents react with TlOEt to give rare, monomeric thallium( I ) complexes in which the Tl I center coordinates to the central nitrogen atom of the W‐shaped triazapentadienyl ligand system (see figure; Ar=2,4,6‐trimethylphenyl; N: blue, F: yellow, Tl: green).