Monomeric Thallium( I ) Complexes of Fluorinated Triazapentadienyl Ligands | Zendy

Dias H. V. Rasika | Zendy; Singh Shreeyukta | Zendy; Cundari Thomas R. | Zendy

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Monomeric Thallium( I ) Complexes of Fluorinated Triazapentadienyl Ligands

Author(s) -

Dias H. V. Rasika,

Singh Shreeyukta,

Cundari Thomas R.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500401

Subject(s) - thallium , monomer , ligand (biochemistry) , aryl , chemistry , atom (system on chip) , stereochemistry , medicinal chemistry , polymer chemistry , combinatorial chemistry , organic chemistry , computer science , biochemistry , operating system , polymer , receptor , alkyl

Rare examples of thallium monocoordination? Polyfluorinated triazapentadienes HN[C(C 3 F 7 )NAr] 2 with bulky aryl substituents react with TlOEt to give rare, monomeric thallium( I ) complexes in which the Tl I center coordinates to the central nitrogen atom of the W‐shaped triazapentadienyl ligand system (see figure; Ar=2,4,6‐trimethylphenyl; N: blue, F: yellow, Tl: green).

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