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A Single‐Crystal‐to‐Single‐Crystal Transformation Mediated by Argentophilic Forces Converts a Finite Metal Complex into an Infinite Coordination Network
Author(s) -
Chu Qianli,
Swenson Dale C.,
MacGillivray Leonard R.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200500400
Subject(s) - single crystal , transformation (genetics) , crystallography , ion , scheme (mathematics) , metal , crystal (programming language) , crystal structure , chemistry , materials science , computer science , mathematics , mathematical analysis , organic chemistry , biochemistry , programming language , gene
Reactions in crystals : Interactions between Ag I ions are used to preorganize olefins for a regiocontrolled single‐crystal‐to‐single‐crystal (SCSC) [2+2] photodimerization that results in a quantitative conversion of a finite dinuclear complex into a one‐dimensional coordination network (see scheme).