2,2′:6′,2′′:6′′,6‐Trioxytriphenylamine: Synthesis and Properties of the Radical Cation and Neutral Species | Zendy

Kuratsu Masato | Zendy; Kozaki Masatoshi | Zendy; Okada Keiji | Zendy

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2,2′:6′,2′′:6′′,6‐Trioxytriphenylamine: Synthesis and Properties of the Radical Cation and Neutral Species

Author(s) -

Kuratsu Masato,

Kozaki Masatoshi,

Okada Keiji

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500397

Subject(s) - radical ion , triphenylamine , chemistry , radical , radical cyclization , planar , oxygen , hydroxyl radical , photochemistry , stereochemistry , ion , organic chemistry , computer graphics (images) , computer science

A flat radical : Oxygen‐bridged triphenylamine 1 and its radical cation 2 were prepared. The neutral compound has a shallow bowl structure, whereas the radical cation is planar. The properties of the highly stable radical cation were clarified; such compounds have potential applicability in electronic and magnetic materials.

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