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2,2′:6′,2′′:6′′,6‐Trioxytriphenylamine: Synthesis and Properties of the Radical Cation and Neutral Species
Author(s) -
Kuratsu Masato,
Kozaki Masatoshi,
Okada Keiji
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200500397
Subject(s) - radical ion , triphenylamine , chemistry , radical , radical cyclization , planar , oxygen , hydroxyl radical , photochemistry , stereochemistry , ion , organic chemistry , computer graphics (images) , computer science
A flat radical : Oxygen‐bridged triphenylamine 1 and its radical cation 2 were prepared. The neutral compound has a shallow bowl structure, whereas the radical cation is planar. The properties of the highly stable radical cation were clarified; such compounds have potential applicability in electronic and magnetic materials.