An Artificial Riboflavin Receptor Prepared by a Template Analogue Imprinting Strategy | Zendy

Manesiotis Panagiotis | Zendy; Hall Andrew J. | Zendy; Courtois Julien | Zendy; Irgum Knut | Zendy; Sellergren Börje | Zendy

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An Artificial Riboflavin Receptor Prepared by a Template Analogue Imprinting Strategy

Author(s) -

Manesiotis Panagiotis,

Hall Andrew J.,

Courtois Julien,

Irgum Knut,

Sellergren Börje

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500342

Subject(s) - riboflavin , isothermal microcalorimetry , receptor , chemistry , population , hydrogen bond , molecular imprinting , combinatorial chemistry , biochemistry , organic chemistry , selectivity , physics , molecule , thermodynamics , medicine , environmental health , enthalpy , catalysis

Cheers! Specificity for riboflavin in water‐rich media with an affinity on the order found for the corresponding biological receptor, riboflavin binding protein, is shown by a receptor containing a complementary hydrogen bonding array (see picture). Microcalorimetry performed at low receptor concentrations in a solution mimicking an alcoholic beverage indicated the presence of a small but uniform population of high‐affinity sites ( K >10 6 M −1 ).

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