Terminal Borylene Complexes Stabilized by a Transition‐Metal Base | Zendy

Braunschweig Holger | Zendy; Rais Daniela | Zendy; Uttinger Katharina | Zendy

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Terminal Borylene Complexes Stabilized by a Transition‐Metal Base

Author(s) -

Braunschweig Holger,

Rais Daniela,

Uttinger Katharina

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500302

Subject(s) - chemistry , transition metal , terminal (telecommunication) , reactivity (psychology) , ligand (biochemistry) , base (topology) , stereochemistry , metal , crystallography , organic chemistry , catalysis , telecommunications , mathematical analysis , mathematics , computer science , medicine , biochemistry , alternative medicine , receptor , pathology

The heat is on : In the first instance of thermal reactivity of the terminal borylenes [(OC) 5 MBN(SiMe 3 ) 2 ] (M=Cr, W), the new heterodinuclear complexes [(OC) 4 M(μ‐CO){μ‐BN(SiMe 3 ) 2 }Pd(PCy 3 )] (see structure; M=Cr) are synthesized. The compounds feature a semibridging borylene ligand and, by virtue of the dative PdB bonding interaction, represent the only examples of terminal borylene species stabilized by a transition‐metal base.

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