Studies toward the Synthesis of Azadirachtin, Part 2: Construction of Fully Functionalized ABCD Ring Frameworks and Unusual Intramolecular Reactions Induced by Close‐Proximity Effects | Zendy

Nicolaou K. C. | Zendy; Sasmal Pradip K. | Zendy; Koftis Theocharis V. | Zendy; Converso Antonella | Zendy; Loizidou Eriketi | Zendy; Kaiser Florian | Zendy; Roecker A. J. | Zendy; Dellios Constantinos C. | Zendy; Sun XiaoWen | Zendy; Petrovic Goran | Zendy

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Studies toward the Synthesis of Azadirachtin, Part 2: Construction of Fully Functionalized ABCD Ring Frameworks and Unusual Intramolecular Reactions Induced by Close‐Proximity Effects

Author(s) -

Nicolaou K. C.,

Sasmal Pradip K.,

Koftis Theocharis V.,

Converso Antonella,

Loizidou Eriketi,

Kaiser Florian,

Roecker A. J.,

Dellios Constantinos C.,

Sun XiaoWen,

Petrovic Goran

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500217

Subject(s) - azadirachtin , intramolecular force , total synthesis , ring (chemistry) , chemistry , stereochemistry , combinatorial chemistry , nanotechnology , organic chemistry , pesticide , materials science , biology , ecology

The remarkable antifeedant agent and insecticide, azadirachtin ( 1 ), has, to date, escaped a total synthesis. The preparation of an advanced precursor has revealed some of the inner intricacies of this uniquely crowded and highly functionalized molecular architecture.

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