{Sn[Zn 4 Sn 4 S 17 ]} 6− : A Robust Open Framework Based on Metal‐Linked Penta‐Supertetrahedral [Zn 4 Sn 4 S 17 ] 10−  Clusters with Ion‐Exchange Properties | Zendy

Manos Manolis J. | Zendy; Iyer Ratnasabapathy G. | Zendy; Quarez Eric | Zendy; Liao J. H. | Zendy; Kanatzidis Mercouri G. | Zendy

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{Sn[Zn 4 Sn 4 S 17 ]} 6− : A Robust Open Framework Based on Metal‐Linked Penta‐Supertetrahedral [Zn 4 Sn 4 S 17 ] 10− Clusters with Ion‐Exchange Properties

Author(s) -

Manos Manolis J.,

Iyer Ratnasabapathy G.,

Quarez Eric,

Liao J. H.,

Kanatzidis Mercouri G.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500214

Subject(s) - ion , zinc , tin , metal , crystallography , inorganic chemistry , ion exchange , chemistry , materials science , analytical chemistry (journal) , metallurgy , organic chemistry , chromatography

Like zeolites , K 6 Sn[Zn 4 Sn 4 S 17 ] (see structure) has remarkable ion‐exchange properties and forms CsK 5 Sn[Zn 4 Sn 4 S 17 ] and RbK 5 Sn[Zn 4 Sn 4 S 17 ] in the presence of the Cs + and Rb + ions, respectively. These compounds have an open framework comprising [Zn 4 Sn 4 S 17 ] 10− clusters linked by Sn 4+ centers and are remarkably stable. One‐fifth of the K + ions play an important templating role in stabilizing the framework. Zn blue, Sn red, S yellow, K orange.

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