Hierarchical Assembly of {Fe 13 } Oxygen‐Bridged Clusters into a Close‐Packed Superstructure | Zendy

Murugesu Muralee | Zendy; Clérac Rodolphe | Zendy; Wernsdorfer Wolfgang | Zendy; Anson Christopher E. | Zendy; Powell Annie K. | Zendy

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Hierarchical Assembly of {Fe 13 } Oxygen‐Bridged Clusters into a Close‐Packed Superstructure

Author(s) -

Murugesu Muralee,

Clérac Rodolphe,

Wernsdorfer Wolfgang,

Anson Christopher E.,

Powell Annie K.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500208

Subject(s) - crystallography , superstructure , crystal structure , close packing of equal spheres , materials science , lattice (music) , oxygen , chemistry , nanotechnology , physics , engineering , organic chemistry , structural engineering , acoustics

Iron aggregates are arranged into a close‐packed structure through coordination bonds to give a material that displays a structural and magnetic hierarchy. The tripodal proligand nitrilotripropionic acid (H 3 ntp=N(CH 2 CH 2 COOH) 3 ) successfully traps {Fe 13 } aggregates, thus producing a lattice that displays three levels of organization (see picture of its 3D packing arrangement; Fe green; O red; N blue; C black; H white).

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