Vapochromic Behavior Accompanied by Phase Transition between Charge‐Polarization and Charge‐Density‐Wave States in a Quasi‐One‐Dimensional Iodine‐Bridged Dinuclear Platinum Compound | Zendy

Mastuzaki Hiroyuki | Zendy; Kishida Hideo | Zendy; Okamoto Hiroshi | Zendy; Takizawa Kouichi | Zendy; Matsunaga Satoshi | Zendy; Takaishi Shinya | Zendy; Miyasaka Hitoshi | Zendy; Sugiura Kenichi | Zendy; Yamashita Masahiro | Zendy

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Vapochromic Behavior Accompanied by Phase Transition between Charge‐Polarization and Charge‐Density‐Wave States in a Quasi‐One‐Dimensional Iodine‐Bridged Dinuclear Platinum Compound

Author(s) -

Mastuzaki Hiroyuki,

Kishida Hideo,

Okamoto Hiroshi,

Takizawa Kouichi,

Matsunaga Satoshi,

Takaishi Shinya,

Miyasaka Hitoshi,

Sugiura Kenichi,

Yamashita Masahiro

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500091

Subject(s) - diamagnetism , polarization (electrochemistry) , charge density wave , halogen , platinum , phase transition , paramagnetism , charge density , chemistry , materials science , crystallography , condensed matter physics , molecular physics , physics , magnetic field , organic chemistry , catalysis , alkyl , superconductivity , quantum mechanics

Color sense : A reversible phase transition occurs with a change in color and structural properties on exposure to water vapor of the 1D halogen‐bridged dinuclear platinum compound [NH 3 (C 4 H 8 )NH 3 ] 2 [Pt 2 (pop) 4 I]⋅4 H 2 O (pop=P 2 O 5 H 2 2− ; see microscope images in reflection mode). This transition takes place between a paramagnetic charge‐polarization state (296 K) and a diamagnetic charge‐density‐wave state (340 K).

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