Strong Means Slow: Dynamic Contributions to the Bulk Mechanical Properties of Supramolecular Networks | Zendy

Yount Wayne C. | Zendy; Loveless David M. | Zendy; Craig Stephen L. | Zendy

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Strong Means Slow: Dynamic Contributions to the Bulk Mechanical Properties of Supramolecular Networks

Author(s) -

Yount Wayne C.,

Loveless David M.,

Craig Stephen L.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500026

Subject(s) - supramolecular chemistry , content (measure theory) , link (geometry) , chemistry , series (stratigraphy) , computer science , chemical physics , molecule , mathematics , organic chemistry , computer network , mathematical analysis , paleontology , biology

Hold on tight : The dynamics, rather than thermodynamics, of reversible cross‐links are the primary determinants of bulk viscosities in a family of supramolecular networks. This result comes from a study in which a series of structurally similar pincer complexes (see picture, OTf=CF 3 SO 3 − ) that have different ligand‐exchange dynamics is used to cross‐link poly(4‐vinylpyridine).

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