Benzene Formation at 70 °C by Coupling of Propylene on Supported Pd Nanoclusters | Zendy

Chou Ju | Zendy; Zhang Siyan | Zendy; Sun Shouli | Zendy; McFarland Eric W. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Benzene Formation at 70 °C by Coupling of Propylene on Supported Pd Nanoclusters

Author(s) -

Chou Ju,

Zhang Siyan,

Sun Shouli,

McFarland Eric W.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500022

Subject(s) - nanoclusters , benzene , catalysis , hydrogen , selectivity , metal , atmospheric pressure , photochemistry , materials science , oxygen , cluster (spacecraft) , inorganic chemistry , chemistry , chemical engineering , nanotechnology , organic chemistry , metallurgy , physics , computer science , programming language , meteorology , engineering

The pressure's off : The coupling of propylene ( 1 ) to generate benzene ( 2 ) at 70 °C and atmospheric pressure was observed together with propylene hydrogenation and oxygenation on titania‐supported Pd nanoclusters (in green). The catalysts consist predominately of metallic Pd 0 . The selectivity of benzene formation is dependent on cluster size (Ø=3–12 nm) and the presence of both hydrogen and oxygen.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research