Introduction of Multiple Elements of Chirality around an Aromatic Core and an Approach to Enantiomerically Pure  C  3 ‐Symmetric Ligands | Zendy

Castaldi M. Paola | Zendy; Gibson Susan E. | Zendy; Rudd Matthew | Zendy; White Andrew J. P. | Zendy

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Introduction of Multiple Elements of Chirality around an Aromatic Core and an Approach to Enantiomerically Pure C 3 ‐Symmetric Ligands

Author(s) -

Castaldi M. Paola,

Gibson Susan E.,

Rudd Matthew,

White Andrew J. P.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500020

Subject(s) - stereocenter , chirality (physics) , core (optical fiber) , scheme (mathematics) , base (topology) , stereochemistry , chemistry , physics , enantioselective synthesis , mathematics , organic chemistry , catalysis , quantum mechanics , optics , chiral symmetry , mathematical analysis , quark , nambu–jona lasinio model

Chiral‐base chemistry has been used to introduce multiple elements of chirality around an (arene)tricarbonylchromium( 0 ) complex. Three stereogenic centers could be installed in one operation to synthesize a nonracemic chiral C 3 ‐symmetric triphosphine and a nonracemic chiral C 3 ‐symmetric tripyridine (see scheme).

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