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Rare and Diverse Binding Modes Introduced through Mechanical Bonding
Author(s) -
Leigh David A.,
Lusby Paul J.,
Slawin Alexandra M. Z.,
Walker D. Barney
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200500004
Subject(s) - catenane , rotaxane , orange (colour) , chemistry , polymer science , crystallography , non covalent interactions , nanotechnology , stereochemistry , materials science , molecule , supramolecular chemistry , crystal structure , organic chemistry , hydrogen bond , food science
Any which way, but not loose : A range of diverse noncovalent binding interactions are observed with a [2]rotaxane (see structure) and a [2]catenane that are not found with similar but not mechanically interlocked fragments. (C (macrocycle) turquoise, other C atoms yellow, O red, N blue, H gray, F green, S orange.)