Dimetallic Dioxygen Activation Leading to a Doubly Oxygen‐Bridged Dirhodium Complex | Zendy

Tejel Cristina | Zendy; Ciriano Miguel A. | Zendy; Sola Eduardo | Zendy; del Río M. Pilar | Zendy; RíosMoreno Gustavo | Zendy; Lahoz Fernando J. | Zendy; Oro Luis A. | Zendy

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Dimetallic Dioxygen Activation Leading to a Doubly Oxygen‐Bridged Dirhodium Complex

Author(s) -

Tejel Cristina,

Ciriano Miguel A.,

Sola Eduardo,

del Río M. Pilar,

RíosMoreno Gustavo,

Lahoz Fernando J.,

Oro Luis A.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200463073

Subject(s) - chemistry , alkene , catalysis , rhodium , iridium , reactivity (psychology) , photochemistry , oxygen , oxidative addition , reductive elimination , polymer chemistry , combinatorial chemistry , organic chemistry , medicine , alternative medicine , pathology

Ready cleavage of dioxygen and its selective insertion into Rh–alkene bonds occurs in the presence of [{Rh(PhN 3 Ph)(C 8 H 12 )} n ] ( n =1 and 2). The structure of the resulting dirhodadioxetane complex (see picture) and kinetic measurements support a dimetallic mechanism for this process that occurs with 100 % atom economy.

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