Tuning a Metal's Oxidation State: The Potential of Clathrochelate Systems | Zendy

Voloshin Yan Z. | Zendy; Varzatskii Oleg A. | Zendy; Vorontsov Ivan I. | Zendy; Antipin Mikhail Yu. | Zendy

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Tuning a Metal's Oxidation State: The Potential of Clathrochelate Systems

Author(s) -

Voloshin Yan Z.,

Varzatskii Oleg A.,

Vorontsov Ivan I.,

Antipin Mikhail Yu.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200463070

Subject(s) - phosphonium , acetonitrile , chemistry , yield (engineering) , ligand (biochemistry) , halide , oxidation state , cobalt , metal , polymer chemistry , photochemistry , inorganic chemistry , organic chemistry , materials science , receptor , biochemistry , metallurgy

A grip on what's inside : A clathrochelate ligand controls the oxidation state of the encapsulated cobalt ion in complex 1 . This complex can be reduced chemically in acetonitrile solution by treatment with silver in the presence of tetraalkylammonium or tetra(dimethylamido)phosphonium halides to the dark‐blue reduced complex [(NMe 2 ) 4 P]‐ 1 in high yield (see scheme).

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