A Ligand Composed of Dinitrogen and Methyldiphenylphosphane in a Cationic Molybdenum Complex | Zendy

Murahashi Tetsuro | Zendy; Clough Christopher R. | Zendy; Figueroa Joshua S. | Zendy; Cummins Christopher C. | Zendy

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A Ligand Composed of Dinitrogen and Methyldiphenylphosphane in a Cationic Molybdenum Complex

Author(s) -

Murahashi Tetsuro,

Clough Christopher R.,

Figueroa Joshua S.,

Cummins Christopher C.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200463057

Subject(s) - molybdenum , cationic polymerization , ligand (biochemistry) , chemistry , coordination sphere , phosphorane , diazo , inorganic chemistry , stereochemistry , combinatorial chemistry , medicinal chemistry , crystallography , polymer chemistry , crystal structure , receptor , biochemistry

Dinitrogen connects molybdenum and phosphorus : The diazo(triorgano)phosphorane ligand Ph 2 MePN 2 is multiply bonded through its N‐terminus to molybdenum in the depicted cationic complex. The Ph 2 MePN 2 ligand was synthesized within molybdenum's coordination sphere by rational assembly from a precursor N 2 complex. Computational studies reveal the NN bond to be highly activated in the complex, which nonetheless readily fragments (with N 2 loss) upon one‐electron reduction.

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