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Organic–Inorganic Hybrid Sol–Gel Materials Incorporating Functionalized Cobalt( III ) Corroles for the Selective Detection of CO
Author(s) -
Barbe JeanMichel,
Canard Gabriel,
Brandès Stéphane,
Guilard Roger
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200463009
Subject(s) - corrole , cobalt , adsorption , sol gel , chemical engineering , nanotechnology , chemistry , materials science , inorganic chemistry , organic chemistry , engineering
Selective adsorption of CO over N 2 and O 2 by the title compounds make these materials ideal candidates for use in CO sensors (see picture). The materials are prepared by a sol–gel process and exhibit greater chemical stability than analogous isolated cobalt( III ) corrole complexes.
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