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Metal Ions Play Different Roles in the Third‐Order Nonlinear Optical Properties of d 10 Metal–Organic Clusters
Author(s) -
Hou Hongwei,
Wei Yongli,
Song Yinglin,
Mi Liwei,
Tang Mingsheng,
Li Linke,
Fan Yaoting
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200463004
Subject(s) - metal , nonlinear optical , ligand (biochemistry) , order (exchange) , atom (system on chip) , metal ions in aqueous solution , nonlinear system , physics , ion , chemistry , crystallography , chemical physics , nanotechnology , materials science , quantum mechanics , computer science , organic chemistry , receptor , biochemistry , embedded system , finance , economics
The heavy‐atom effect cannot explain the difference in the third‐order nonlinear optical properties of the clusters [Ag 10 (dcapp) 4 ](OH) 2 ⋅12 H 2 O ( 1 , see structure), [Zn 4 O(dcapp) 3 ]⋅6 H 2 O ( 2 ), and [Hg 2 (dcapp) 2 ] ( 3 ) (H 2 dcapp=2,6‐dicarboxamido‐2‐pyridylpyridine). Quantum chemical calculations show that the NLO properties of 1 are controlled both by the metal and the ligand, while those of 2 and 3 are controlled by the ligand only.
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