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Supramolecular Interactions as Determining Factors of the Geometry of Metallic Building Blocks: Tetracarboxylate Dimanganese Species
Author(s) -
Grirrane Abdessamad,
Pastor Antonio,
Galindo Agustín,
del Río Diego,
Orlandini Annabella,
Mealli Carlo,
Ienco Andrea,
Caneschi Andrea,
Fernández Sanz Javier
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462965
Subject(s) - stacking , supramolecular chemistry , manganese , non covalent interactions , coordination geometry , crystallography , chemistry , metal , molecule , crystal structure , organic chemistry , hydrogen bond
Supramolecular structures are generated from manganese thiodiacetate (tda) units and substituted bipyridine (bipy) ligands (see pictures). Analysis of the π‐stacking and DFT calculations for isolated binuclear units suggest that, in some cases, the geometry of the building blocks depends ultimately on the strength of noncovalent interactions between the 1D coordination polymers.