Floating Single Hydrogen Molecule in an Open‐Cage Fullerene | Zendy

Sawa Hiroshi | Zendy; Wakabayashi Yusuke | Zendy; Murata Yasujiro | Zendy; Murata Michihisa | Zendy; Komatsu Koichi | Zendy

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Floating Single Hydrogen Molecule in an Open‐Cage Fullerene

Author(s) -

Sawa Hiroshi,

Wakabayashi Yusuke,

Murata Yasujiro,

Murata Michihisa,

Komatsu Koichi

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200462850

Subject(s) - fullerene , molecule , cage , chemistry , crystallography , synchrotron , derivative (finance) , materials science , chemical physics , physics , organic chemistry , optics , mathematics , combinatorics , financial economics , economics

Open‐mouthed fullerene swallows H 2 whole : Direct observation of a H 2 molecule that is fully encapsulated by a derivative of an aza–thia open‐cage fullerene (see model) is achieved by synchrotron X‐ray diffraction analysis of single crystals. A 3D electron‐density map obtained by the maximum entropy method shows a single H 2 molecule (red) floating in the center of a hollow cavity in the open‐cage fullerene molecule (yellow).

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