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CH Activated Isomers of [M(AlCp*) 5 ] (M=Fe, Ru)
Author(s) -
Steinke Tobias,
Cokoja Mirza,
Gemel Christian,
Kempter Andreas,
Krapp Andreas,
Frenking Gernot,
Zenneck Ulrich,
Fischer Roland A.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462834
Subject(s) - transition metal , content (measure theory) , chemistry , crystallography , stereochemistry , catalysis , organic chemistry , mathematics , mathematical analysis
What are the limits for n in the case of [M(E I R) n ] (M=transition metal; E=Al, Ga, In)? Is n =5 possible, maybe n =6, or even more? A first insight is gained through the reactions of Fe 0 and Ru 0 precursors with excess of AlCp*, leading to CH activated isomers of [M(AlCp*) 5 ] (see picture for M=Fe, gray C, white H, blue Al, red Fe, Cp*=C 5 Me 5 ).