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Stable, Water‐Soluble Pta‐Based Ru–Ag Organometallic Polymers
Author(s) -
Lidrissi Chaker,
Romerosa Antonio,
Saoud Mustapha,
SerranoRuiz Manuel,
Gonsalvi Luca,
Peruzzini Maurizio
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462790
Subject(s) - water soluble , polymer , yield (engineering) , ligand (biochemistry) , polymer chemistry , chemistry , dynamic light scattering , materials science , chemical engineering , polymer science , nanotechnology , organic chemistry , nanoparticle , engineering , composite material , biochemistry , receptor
The cagelike 1,3,5‐triaza‐7‐phosphaadamantane ligand bridges [CpRu] + and [AgCl 2 ] − moieties by an unprecedented N,P‐coordinating mode (see picture) to yield water‐soluble, air‐stable heterobimetallic polymeric structures. The products have been structurally characterized, and dynamic light‐scattering measurements confirm the polymeric nature of the complex in water.