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High H 2 Adsorption in a Microporous Metal–Organic Framework with Open Metal Sites
Author(s) -
Chen Banglin,
Ockwig Nathan W.,
Millward Andrew R.,
Contreras Damacio S.,
Yaghi Omar M.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462787
Subject(s) - microporous material , adsorption , metal organic framework , metal , materials science , inorganic chemistry , chemistry , organic chemistry , metallurgy
A copper‐based metal–organic framework (MOF) has been synthesized, and its structure has been solved by X‐ray crystallography (see picture; Cu blue, C black, O red, framework pore yellow). The remarkably high hydrogen adsorption properties (2.47 wt %) of this compound have been studied.