Synthesis, Reactivity, and Structural Characterization of a 14‐Vertex Carborane | Zendy

Deng Liang | Zendy; Chan HoiShan | Zendy; Xie Zuowei | Zendy

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Synthesis, Reactivity, and Structural Characterization of a 14‐Vertex Carborane

Author(s) -

Deng Liang,

Chan HoiShan,

Xie Zuowei

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200462708

Subject(s) - carborane , reactivity (psychology) , characterization (materials science) , vertex (graph theory) , chemistry , materials science , stereochemistry , combinatorics , nanotechnology , mathematics , medicine , graph , alternative medicine , pathology

The largest known carborane , which has 14 vertices, was prepared by the reaction of arachno ‐carborane tetraanion 1 with HBBr 2 ⋅SMe 2 (see scheme). The reactivity of both 13‐ ( 2 ) and 14‐vertex carboranes ( 3 and 4 ) has also been examined. The key to the successful preparation of supracarboranes is to block the redox reactions between carborane anions and RBX 2 reagents.

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