Topochemical Photodimerization in the Coordination Polymer [{(CF 3 CO 2 )(μ‐O 2 CCH 3 )Zn} 2 (μ‐bpe) 2 ]  n   through Single‐Crystal to Single‐Crystal Transformation | Zendy

Toh Ni Lian | Zendy; Nagarathinam Mangayarkarasi | Zendy; Vittal Jagadese J. | Zendy

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Topochemical Photodimerization in the Coordination Polymer [{(CF 3 CO 2 )(μ‐O 2 CCH 3 )Zn} 2 (μ‐bpe) 2 ] n through Single‐Crystal to Single‐Crystal Transformation

Author(s) -

Toh Ni Lian,

Nagarathinam Mangayarkarasi,

Vittal Jagadese J.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200462673

Subject(s) - yield (engineering) , cycloaddition , polymer , crystallography , coordination polymer , crystal (programming language) , single crystal , coordination complex , chemistry , materials science , crystal structure , computer science , metal , organic chemistry , metallurgy , catalysis , programming language

The molecular‐ladder‐structured , one‐dimensional Zn–(4,4′‐bipyridylethylene) coordination polymer 1 undergoes [2+2] photochemical cycloaddition across the rails to form 2 in up to 100 % yield, accompanied by a single‐crystal to single‐crystal transformation.

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