Premium
Topochemical Photodimerization in the Coordination Polymer [{(CF 3 CO 2 )(μ‐O 2 CCH 3 )Zn} 2 (μ‐bpe) 2 ] n through Single‐Crystal to Single‐Crystal Transformation
Author(s) -
Toh Ni Lian,
Nagarathinam Mangayarkarasi,
Vittal Jagadese J.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462673
Subject(s) - yield (engineering) , cycloaddition , polymer , crystallography , coordination polymer , crystal (programming language) , single crystal , coordination complex , chemistry , materials science , crystal structure , computer science , metal , organic chemistry , metallurgy , catalysis , programming language
The molecular‐ladder‐structured , one‐dimensional Zn–(4,4′‐bipyridylethylene) coordination polymer 1 undergoes [2+2] photochemical cycloaddition across the rails to form 2 in up to 100 % yield, accompanied by a single‐crystal to single‐crystal transformation.