Premium
Synthesis and Solid‐State Structure of a Metal Complex of a Diphosphineimine
Author(s) -
Anagho Leonard E.,
Bickley Jamie F.,
Steiner Alexander,
Stahl Lothar
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462588
Subject(s) - molybdenum , chemistry , nickel , metal , coordination complex , solid state , combinatorial chemistry , inorganic chemistry , organic chemistry
A stabilizing influence : Heterocyclic diaminophosphines can stabilize diphosphineimines sufficiently to allow the preparation of metal complexes. A kinetically stable diphosphineimine is isolated and its coordination chemistry investigated through the preparation of molybdenum (see picture) and nickel complexes with such PPN ligands.