From Racemic Primary Aminoalkyl(phosphanyl)ferrocene Complexes to a Lithium–Phosphorus  closo  Cluster | Zendy

Tschirschwitz Steffen | Zendy; Lönnecke Peter | Zendy; Reinhold Joachim | Zendy; HeyHawkins Evamarie | Zendy

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From Racemic Primary Aminoalkyl(phosphanyl)ferrocene Complexes to a Lithium–Phosphorus closo Cluster

Author(s) -

Tschirschwitz Steffen,

Lönnecke Peter,

Reinhold Joachim,

HeyHawkins Evamarie

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200462543

Subject(s) - ethylamine , chemistry , lithium (medication) , ferrocene , deprotonation , cluster (spacecraft) , phosphorus , primary (astronomy) , stereochemistry , medicinal chemistry , organic chemistry , electrochemistry , ion , medicine , electrode , computer science , programming language , endocrinology , physics , astronomy

Li 12 P 6 : The first two primary aminoalkyl(phosphanyl)ferrocene complexes 2‐( N , N ‐Dimethylaminomethyl)phosphanylferrocene ( 1 ) and N , N ‐dimethyl‐1‐(2‐phosphanylferrocenyl)ethylamine ( 2 ) are prepared. Compound 1 readily undergoes twofold deprotonation with n BuLi to form the first lithium–phosphorus cluster (see picture) which has the structure and electronic properties of a closo cluster according to Wade's rules.

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