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Metal@MOF: Loading of Highly Porous Coordination Polymers Host Lattices by Metal Organic Chemical Vapor Deposition
Author(s) -
Hermes Stephan,
Schröter MarieKatrin,
Schmid Rochus,
Khodeir Lamma,
Muhler Martin,
Tissler Arno,
Fischer Richard W.,
Fischer Roland A.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462515
Subject(s) - chemical vapor deposition , metal organic framework , polymer , metal , porous medium , metalorganic vapour phase epitaxy , chemistry , deposition (geology) , porosity , group 2 organometallic chemistry , nanotechnology , methanol , catalysis , chemical engineering , materials science , organic chemistry , molecule , epitaxy , paleontology , adsorption , sediment , engineering , biology , layer (electronics)
Precursors and particles captured in a net : Porous coordination polymers such as MOF‐5 are efficient gas storage devices and are also able to absorb metal organic chemical vapor deposition (MOCVD) precursors (see picture, red: [(η 5 ‐C 5 H 5 )Pd(η 3 ‐C 3 H 5 )]). These incorporated compounds are easily reduced to give the corresponding metal nanoparticles. Applications in heterogeneous catalysis, for instance, methanol synthesis or hydrogenation, are described.