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Reversible Transformation of Two Diphenylphosphanido Ligands into the Neutral Tetraphenyldiphosphane Ligand
Author(s) -
Forniés Juan,
Fortuño Consuelo,
Ibáñez Susana,
Martín Antonio,
Tsipis Athanasios C.,
Tsipis Constantinos A.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462498
Subject(s) - bridging (networking) , transformation (genetics) , scheme (mathematics) , computer science , chemistry , ligand (biochemistry) , bridging ligand , combinatorial chemistry , information retrieval , crystallography , mathematics , computer network , biochemistry , receptor , crystal structure , mathematical analysis , gene
From a theoretical prediction to an experimental finding : Oxidation of two bridging diphenylphosphanido ligands to a neutral tetraphenyldiphosphane is predicted theoretically and achieved experimentally in a trinuclear Pt 2 Pd complex (see scheme, R F =C 6 F 5 , P*=PPh 2 ).