Reversible Transformation of Two Diphenylphosphanido Ligands into the Neutral Tetraphenyldiphosphane Ligand | Zendy

Forniés Juan | Zendy; Fortuño Consuelo | Zendy; Ibáñez Susana | Zendy; Martín Antonio | Zendy; Tsipis Athanasios C. | Zendy; Tsipis Constantinos A. | Zendy

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Reversible Transformation of Two Diphenylphosphanido Ligands into the Neutral Tetraphenyldiphosphane Ligand

Author(s) -

Forniés Juan,

Fortuño Consuelo,

Ibáñez Susana,

Martín Antonio,

Tsipis Athanasios C.,

Tsipis Constantinos A.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200462498

Subject(s) - bridging (networking) , transformation (genetics) , scheme (mathematics) , computer science , chemistry , ligand (biochemistry) , bridging ligand , combinatorial chemistry , information retrieval , crystallography , mathematics , computer network , biochemistry , receptor , crystal structure , mathematical analysis , gene

From a theoretical prediction to an experimental finding : Oxidation of two bridging diphenylphosphanido ligands to a neutral tetraphenyldiphosphane is predicted theoretically and achieved experimentally in a trinuclear Pt 2 Pd complex (see scheme, R F =C 6 F 5 , P*=PPh 2 ).

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