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Spin Canting and Metamagnetism in a 3D Homometallic Molecular Material Constructed by Interpenetration of Two Kinds of Cobalt( II )‐Coordination‐Polymer Sheets
Author(s) -
Zeng MingHua,
Zhang WeiXiong,
Sun XianZhong,
Chen XiaoMing
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462463
Subject(s) - metamagnetism , spin canting , cobalt , materials science , polymer , coordination polymer , ion , crystallography , condensed matter physics , nanotechnology , magnetic field , chemistry , composite material , metallurgy , physics , organic chemistry , magnetization , quantum mechanics
Two different types of coordination sheets made up of Co II ions, 3‐hydroxypicolinate, and 4,4′‐bipyridine interpenetrate to form a unique molecular‐based magnetic material (see picture). This material displays a low‐field metamagnetic transition and spin‐canted behavior.