Redox‐Induced Collapse and Regeneration of a Pincer‐Type Complex Framework: A Nonplanar Coordination Mode of Palladium( II ) | Zendy

Frech Christian M. | Zendy; Shimon Linda J. W. | Zendy; Milstein David | Zendy

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Redox‐Induced Collapse and Regeneration of a Pincer‐Type Complex Framework: A Nonplanar Coordination Mode of Palladium( II )

Author(s) -

Frech Christian M.,

Shimon Linda J. W.,

Milstein David

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200462386

Subject(s) - pincer movement , bimetallic strip , palladium , chemistry , diamagnetism , redox , halide , catalysis , combinatorial chemistry , medicinal chemistry , polymer chemistry , photochemistry , stereochemistry , inorganic chemistry , organic chemistry , physics , quantum mechanics , magnetic field

Unequal partners : One‐electron reduction of a pincer‐type palladium complex 1 results in collapse of the pincer system and formation of a novel bimetallic diamagnetic complex containing a linearly coordinated 14 e Pd 0 center and a nonplanar Pd II unit ( 2 ). The reaction is reversed by oxidation with Ag + or organic halides. The catalytic activity of 2 is investigated for the Heck reaction.

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