Premium
[2]Pseudorotaxanes through Second‐Sphere Coordination
Author(s) -
Blight Barry A.,
Van Noortwyk Kevin A.,
Wisner James A.,
Jennings Michael C.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462380
Subject(s) - coordination sphere , chemistry , palladium , metal , crystallography , stereochemistry , crystal structure , organic chemistry , catalysis
A macrocyclic tetralactam and simple trans ‐palladium dihalide complexes self‐assemble to form [2]pseudorotaxanes. The pseudorotaxane superstructures are formed through second‐sphere coordination of the metal ligands by the macrocyclic component (see picture; red: macrocycle with hydrogen atoms removed, blue: n ‐hexylamine, green: Cl, gray: Pd).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom