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A Metal‐Based Lumophore Tailored To Sense Biologically Relevant Oxometalates
Author(s) -
Peacock Anna F. A.,
Batey Helen D.,
Raendler Claudia,
Whitwood Adrian C.,
Perutz Robin N.,
DuhmeKlair AnneK.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462306
Subject(s) - tungstate , catechol , acetonitrile , molybdate , vanadate , aqueous solution , luminescence , conjugate , chemistry , quenching (fluorescence) , pyridine , bipyridine , metal ions in aqueous solution , metal , inorganic chemistry , combinatorial chemistry , materials science , organic chemistry , fluorescence , physics , mathematics , optoelectronics , mathematical analysis , quantum mechanics , crystal structure
Oxometalate detection : A new catechol–[Re I (2,2′‐bpy)(py)(CO) 3 ] + (bpy=bipyridine, py=pyridine) conjugate has been prepared which signals the presence and concentration of molybdate, vanadate, and/or tungstate ions in solution in aqueous acetonitrile by efficient quenching of the Re‐based luminescence (see picture).