Periodic Mesoporous Organosilicas: Self‐Assembly from Bridged Cyclic Silsesquioxane Precursors | Zendy

Landskron Kai | Zendy; Ozin Geoffrey A. | Zendy

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Periodic Mesoporous Organosilicas: Self‐Assembly from Bridged Cyclic Silsesquioxane Precursors

Author(s) -

Landskron Kai,

Ozin Geoffrey A.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200462279

Subject(s) - silsesquioxane , mesoporous organosilica , mesoporous material , copolymer , materials science , self assembly , block (permutation group theory) , nanotechnology , chemical engineering , chemistry , mesoporous silica , organic chemistry , catalysis , polymer , composite material , mathematics , engineering , geometry

No holes barred : Trimethylene‐bridged 1 can be prepared from [{SiCH 2 (OEt) 2 } 3 ]. Compound 1 can be directed to self‐assemble by a tri‐block copolymer template to form a periodic mesoporous organosilica with highly ordered and uniform‐diameter mesopores in which practically all the building blocks remain intact within the as‐synthesized and template‐extracted material.

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