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A Metal–Organic Framework with the Zeolite MTN Topology Containing Large Cages of Volume 2.5 nm 3
Author(s) -
Fang Qianrong,
Zhu Guangshan,
Xue Ming,
Sun Jinyu,
Wei Yen,
Qiu Shilun,
Xu Ruren
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462260
Subject(s) - zeolite , topology (electrical circuits) , volume (thermodynamics) , metal , metal organic framework , content (measure theory) , chemistry , nanotechnology , materials science , organic chemistry , physics , engineering , catalysis , mathematics , thermodynamics , electrical engineering , adsorption , mathematical analysis
If you look for holes , you will find them in a novel 3D metal–organic framework complex with zeolite MTN topology. The framework of [{Cd(H 2 O) 3 } 34 (N 4 C 6 H 12 ) 17 ]Cl 68 ⋅46 H 2 O⋅68 DMF greatly expands the original structure of MTN and contains large cages with a volume of about 2522 Å 3 (see structure). MTN=zeolite socony mobil – thirty‐nine, DMF= N , N ‐dimethylformamide.
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