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Palladium(0)‐Catalyzed Hydroalkoxylation of Hexafluoropropene: Synthesis of Hydrofluoroethers under Neutral Conditions
Author(s) -
Matsukawa Yasuhisa,
Mizukado Junji,
Quan Hengdao,
Tamura Masanori,
Sekiya Akira
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462200
Subject(s) - butane , palladium , catalysis , ether , scheme (mathematics) , phenols , chemistry , organic chemistry , medicinal chemistry , mathematics , mathematical analysis
No vinyl ether by‐products are formed in the palladium( 0 )‐complex catalyzed hydroalkoxylation of hexafluoropropene (see scheme). Saturated hydrofluoroethers are selectively synthesized with alcohols or phenols under neutral conditions in the presence of [Pd(PPh 3 ) 4 ]/dppb. dppb=1,4‐bis(diphenylphosphanyl)butane.