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Telluradistibirane and Telluradibismirane: Three‐Membered Heterocycles of Heavier Main Group Elements
Author(s) -
Sasamori Takahiro,
Mieda Eiko,
Takeda Nobuhiro,
Tokitoh Norihiro
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462122
Subject(s) - cyan , group (periodic table) , chemistry , metal , main group element , crystallography , mathematics , stereochemistry , organic chemistry , transition metal , physics , catalysis , optics
Metal triangles : The first stable telluradistibirane and telluradibismirane derivatives (see structure) have been successfully synthesized by the reaction of an overcrowded distibene (BbtSbSbBbt) and dibismuthene (BbtBiBiBbt) with n Bu 3 PTe, respectively. (C cyan, Si red).