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CH Activation of Alkanes and Arenes Catalyzed by an O‐Donor Bis(tropolonato)iridium( III ) Complex
Author(s) -
Bhalla Gaurav,
Periana Roy A.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462065
Subject(s) - iridium , catalysis , chemistry , medicinal chemistry , alkane , polymer chemistry , stereochemistry , organic chemistry
Stable and swift : The title complex is stable to air and water under thermal conditions. It efficiently activates the CH bonds of alkanes and arenes at rates 50 times higher than does the only previously reported O‐donor Ir III complex (see picture).