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One‐Pot Conversion of Phospholide Ions into β‐Functional Phosphinines
Author(s) -
Grundy Joanna,
Mathey François
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462020
Subject(s) - ion , reactivity (psychology) , class (philosophy) , chemistry , mechanism (biology) , scheme (mathematics) , computer science , combinatorial chemistry , mathematics , organic chemistry , artificial intelligence , epistemology , philosophy , medicine , alternative medicine , pathology , mathematical analysis
Only a few β‐functional phosphinines are known. As a result, the reactivity of this class of compounds is almost unexplored. A straightforward access to such compounds from the readily available phospholide ions is described (see scheme) and the reaction mechanism is explored by theoretical methods.