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Iron‐Catalyzed Aryl–Aryl Cross‐Couplings with Magnesium‐Derived Copper Reagents
Author(s) -
Sapountzis Ioannis,
Lin Wenwei,
Kofink Christiane C.,
Despotopoulou Christina,
Knochel Paul
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200462013
Subject(s) - aryl , magnesium , reagent , nitrile , trifluoromethanesulfonate , catalysis , copper , chemistry , combinatorial chemistry , function (biology) , organic chemistry , medicinal chemistry , biology , alkyl , evolutionary biology
Well‐matched couples : Functionalized aryl and heteroaryl copper species obtained from the corresponding magnesium derivatives undergo Fe‐catalyzed cross‐coupling reactions with aryl iodides that bear keto, ester, triflate, or nitrile groups (see scheme).