A Fluorous‐Phase Pummerer Cyclative‐Capture Strategy for the Synthesis of Nitrogen Heterocycles | Zendy

McAllister Laura A. | Zendy; McCormick Rosemary A. | Zendy; Brand Stephen | Zendy; Procter David J. | Zendy

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A Fluorous‐Phase Pummerer Cyclative‐Capture Strategy for the Synthesis of Nitrogen Heterocycles

Author(s) -

McAllister Laura A.,

McCormick Rosemary A.,

Brand Stephen,

Procter David J.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461930

Subject(s) - phase (matter) , catalysis , combinatorial chemistry , cleavage (geology) , chemistry , coupling (piping) , throughput , nitrogen , computer science , organic chemistry , materials science , telecommunications , fracture (geology) , metallurgy , composite material , wireless

Catching on : Fluorous‐tagged heterocyclic frameworks accessed rapidly through a Pummerer cyclative‐capture approach can then be modified conveniently, for example, by Pd‐catalyzed cross‐coupling. Traceless, reductive cleavage of the fluorous phase tag completes a strategy for the high‐throughput, fluorous‐phase synthesis of N heterocycles (see scheme, R F =C 8 F 17 CH 2 CH 2 ).

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