Premium
Isotopomeric Conformational Change in Anisole–Water
Author(s) -
Giuliano Barbara M.,
Caminati Walther
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461860
Subject(s) - anisole , conformational change , value (mathematics) , chemistry , chemical engineering , computer science , stereochemistry , organic chemistry , engineering , machine learning , catalysis
The deuteration of water produces the conformational change shown in the figure in the anisole⋅⋅⋅water complex. The value of the θ angle decreases from 138 to 128°, and the secondary interaction O⋅⋅⋅H Me is replaced by O⋅⋅⋅H Ph .