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Template‐Assisted Cross Olefin Metathesis
Author(s) -
Yang Xiaowu,
Gong Bing
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461777
Subject(s) - alkene , metathesis , olefin metathesis , intermolecular force , chemistry , catalysis , stereochemistry , polymer science , combinatorial chemistry , organic chemistry , molecule , polymerization , polymer
Making ends meet : Alkene units tethered to two complementary oligoamide strands, which pair sequence‐specifically into hydrogen‐bonded duplexes, undergo intermolecular cross‐metathesis when the two alkene moieties are in close proximity upon heating in the presence of Grubbs' catalyst (see graphic).