Bond‐Selective H −  Ion Abstraction from Thymine | Zendy

Ptasińska Sylwia | Zendy; Denifl Stephan | Zendy; Grill Verena | Zendy; Märk Tilmann D. | Zendy; Scheier Paul | Zendy; Gohlke Sascha | Zendy; Huels Michael A. | Zendy; Illenberger Eugen | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Bond‐Selective H − Ion Abstraction from Thymine

Author(s) -

Ptasińska Sylwia,

Denifl Stephan,

Grill Verena,

Märk Tilmann D.,

Scheier Paul,

Gohlke Sascha,

Huels Michael A.,

Illenberger Eugen

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461739

Subject(s) - thymine , ion , yield (engineering) , deuterium , abstraction , chemistry , range (aeronautics) , electron , dna , atomic physics , materials science , physics , nuclear physics , organic chemistry , composite material , biochemistry , philosophy , epistemology , metallurgy

The attachment of free electrons to thymine in the gas phase leads to the abstraction of H − ions and a broad, structured feature in the energy range between 5 and 12 eV (see picture). In experiments with partly deuterated thymine the different peaks in the H − ion yield were shown to be associated unambiguously with abstraction from the different molecular positions. This reaction may be an important initial step towards DNA strand breaks.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research