Tungsten–Lead Triple Bonds: Syntheses, Structures, and Coordination Chemistry of the Plumbylidyne Complexes  trans ‐[X(PMe 3 ) 4 WPb(2,6‐Trip 2 C 6 H 3 )] | Zendy

Filippou Alexander C. | Zendy; Weidemann Nils | Zendy; Schnakenburg Gregor | Zendy; Rohde Holger | Zendy; Philippopoulos Athanassios I. | Zendy

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Tungsten–Lead Triple Bonds: Syntheses, Structures, and Coordination Chemistry of the Plumbylidyne Complexes trans ‐[X(PMe 3 ) 4 WPb(2,6‐Trip 2 C 6 H 3 )]

Author(s) -

Filippou Alexander C.,

Weidemann Nils,

Schnakenburg Gregor,

Rohde Holger,

Philippopoulos Athanassios I.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461725

Subject(s) - carbyne , tungsten , triple bond , chemistry , crystallography , derivative (finance) , trimethylphosphine , quantum chemical , molecule , crystal structure , stereochemistry , double bond , polymer chemistry , carbene , organic chemistry , catalysis , economics , financial economics

Plumb line : A series of compounds trans ‐[L(PMe 3 ) 4 WPb(2,6‐Trip 2 C 6 H 3 )] n + ( n =0: L=Br, I; n =1: L=PhCN, PMe 3 ; Trip=2,4,6‐ i Pr 3 C 6 H 2 ; see structure of L=PMe 3 derivative) containing WPb triple bonds is reported. Quantum‐chemical analyses of the WPb bond in the plumbylidyne complex [(PMe 3 ) 5 WPb(2,6‐Trip 2 C 6 H 3 )] + confirm the electronic analogy with Fischer‐type carbyne complexes.

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