New Structural Motifs in Manganese Single‐Molecule Magnetism from the Use of Triethanolamine Ligands | Zendy

Murugesu Muralee | Zendy; Wernsdorfer Wolfgang | Zendy; Abboud Khalil A. | Zendy; Christou George | Zendy

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New Structural Motifs in Manganese Single‐Molecule Magnetism from the Use of Triethanolamine Ligands

Author(s) -

Murugesu Muralee,

Wernsdorfer Wolfgang,

Abboud Khalil A.,

Christou George

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461703

Subject(s) - triethanolamine , manganese , magnetism , molecule , crystallography , chemistry , ligand (biochemistry) , magnet , materials science , stereochemistry , nanotechnology , physics , condensed matter physics , organic chemistry , receptor , quantum mechanics , analytical chemistry (journal) , biochemistry

Saddle seen : The use of the potentially tetradentate triethanolamine (teaH 3 ) ligand provides a useful route to three new structural types in mixed‐valent manganese cluster chemistry, which include near‐rectangular and closed‐sinusoidal (saddle‐shaped; see structure: Mn III purple, Mn II yellow, O red, N blue, C gray) topologies. Further, two of these complexes are also new single‐molecule magnets (SMMs).

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