Premium
Synthesis of Hexa‐ and Dodecanuclear Organoaluminum Ring Structures Incorporating the “Magic” Ph 2 C(X) Group (X=O − , NH − )
Author(s) -
Redshaw Carl,
Elsegood Mark R. J.,
Holmes Kathryn E.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461627
Subject(s) - magic (telescope) , hexa , ring (chemistry) , crystallography , chemistry , stereochemistry , group (periodic table) , physics , organic chemistry , astronomy
The magic touch! By using the “magic” group Ph 2 C(X) (X=O − , NH − ), aluminum ring systems such as 1 have been synthesized from trimethylaluminum. For diphenylglycine (X=NH − ), both six‐ and twelve‐membered rings have been structurally identified.